Identification of Microplastics in Environmental Monitoring Using Pyrolysis–GC–MS Analysis

Microplastics (MPs) are tiny plastic particles that measure less than five millimeters across. As a pollutant, microplastics harm the environment and animal health. Microplastics are extremely persistent, meaning removing them from the environment where they accumulate is almost impossible. Due to their persistence nature and the chemicals, they are composed of, studies suggest that they can be highly detrimental to the organisms that come into contact with them, leading to reduced feeding, poisoning, increasing mortality, and other harmful effects.

Qualitative Additive analysis of tire rubber using Py-GCMS
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Workflow for Microplastics Analysis with Py-GC/MS System

Step 1 Sampling and pretreatment

Microplastics are extracted from environmental samples by appropriate pretreatment and then homogenized using Cryogenic Mill (IQ-MILL 2070E) or a mixer. The sample is then placed in a sample cup and weighed using a semimicro balance.

Step 2 Set of the sample cup on the Auto-Shot Sampler

The sample cups are placed onto the Auto-Shot Sampler. Up to 48 cups can be loaded each time.

Step 3 Pyrolysis of the sample

The sample is introduced into the Micro-Furnace pyrolyzer by the Auto-Shot Sampler and is pyrolyzed. The plastics become pyrolysis products (pyrolyzates) and are introduced into the GC directly. On the other hand, the inorganics in the sample remain in the sample cup as residues.

Step 4 GC/MS analysis

Pyrolyzates are separated on a GC column and detected by a single Quadrupole mass spectrometer. The resulting pyrogram generally includes a peak for each pyrolyzate. The mass spectrum from each peak reflects the chemical structure of each pyrolyzate. Each polymer generates a unique set of pyrolyzates.

Step 5 Data analysis

Reliable and quick Data analysis can be done using F-Search MPs 2.0. Calibration curves are created automatically based on the analytical results from the reference polymer mixture. Then F-Search MPs 2.0 performs quantitative calculation automatically and results are reported for each sample.

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Micro-Furnace Pyrolysis-GC/MS System

Microplastics Analysis

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